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Rising Toward a Cleaner Future: Pennsylvania’s CCS Ladder for Industrial Decarbonization

Clean Energy

After presenting the broad picture of carbon capture and storage (CCS) prioritization in the United States, we now investigate the specific case of Pennsylvania, as the state is funding multiple decarbonization projects. Here is a look at decarbonization strategies, with details on the state’s top industry: steel.

Pennsylvania has led U.S. energy generation from coal mining to oil and natural gas production from Marcellus shale. Pennsylvania has also played a leadership role in critical industrial sectors like steel and cement. Now, the state works to preserve its leadership role by transitioning to lower-carbon energy resources and deploying comprehensive industrial decarbonization strategies through the RISE PA program.

Previously, our team from Penn’s Clean Energy Conversions Lab developed a CCS ladder for the U.S., identifying sectors to be prioritized for CCS deployment. Here, we present a CCS ladder and recommendations specific to Pennsylvania (Figure 1).

Figure 1: Pennsylvania CCS ladder for industrial decarbonization
This figure is a pie chart of greenhouse gas emissions from industrial sectors in the
Pennsylvania. Each slice represents one industrial sector (iron & steel, cement, lime, glass,  refining, ethylene, pulp & paper). Each of the industrial sectors is divided into two slices, the first showing the carbon capture potential and the second the portion of the emissions that is remaining and can be decarbonized through alternative decarbonization pathways. For each industrial sector, three numbers are given: (1) the total greenhouse gas emissions of the sector in million metric tons of CO2 equivalent per year, (2) the carbon capture and storage (CCS) potential for the sector in million metric tons of CO2 per year, and (3) the remaining greenhouse gas emissions in million metric tons of CO2 equivalent per year, that can be decarbonized through alternative decarbonization pathways. For each sector, these numbers are the following.
●	Iron & steel makes 40.6% of the pie: total emissions are 6.07 million tons of CO2 per year, CCS potential is 5.22, and remaining emissions: 0.85
●	Cement makes 19.6% of the pie: total emissions are 2.93 million tons of CO2 per year, CCS potential is 2.78, and remaining emissions: 0.15
●	Lime makes 6.8% of the pie: total emissions are 1.02 million tons of CO2 per year, CCS potential is 0.97, and remaining emissions: 0.05
●	Glass makes 3.4% of the pie: total emissions are 0.5 million tons of CO2 per year, CCS potential is 0.48, and remaining emissions: 0.03
●	Refining makes 13.1% of the pie: total emissions are 1.96 million tons of CO2 per year, CCS potential is 1.50, and remaining emissions: 0.46. In this case the CCS potential assumes that refineries produce more hydrogen with CCS, to use on site as a source of decarbonized heat.
●	Ethylene makes 4.8% of the pie: total emissions are 0.72 million tons of CO2 per year, CCS potential is 0.33, and remaining emissions: 0.39
●	Pulp & paper makes 11.5% of the pie: total emissions are 1.72 million tons of CO2 per year, CCS potential is 1.52, and remaining emissions are: 0.2
Figure 2: Greenhouse gas emissions from large emitting industries (iron & steel, cement, lime, glass, refining, ethylene, and paper production) in Pennsylvania. Solid color blocks are emissions that can be captured at the facility; speckled color blocks represent remaining emissions.

Steel makes up 40% of Pennsylvania’s industrial emissions. With 18 facilities in the state, and almost 200 years of steel expertise, Pennsylvania is ripe for steel decarbonization. It is also taking first steps toward it with a recently awarded carbon capture project at U.S. Steel’s Edgar Thomson facility ($8.85M) and a furnace electrification demonstration project led by Cleveland-Cliffs’ Butler Works (up to $75M).

Strategic allocation of funding through RISE PA with suggestions from this ladder can potentially set Pennsylvania apart and lead industrial emissions reductions. In our U.S.-scale CCS ladder, we recommended CCS as a transition solution in steel decarbonization.

Pennsylvania exemplifies this path. CCS at the Edgar Thompson facility will reduce emissions in the short-to-medium term. Blast furnaces like those at Edgar Thompson can last 15–20 years, however are often in operation long after this, given maintenance is not economically prohibitive, and carbon capture is typically financed over 30 years.

These near-term emissions reductions allow the Appalachian and Mid-Atlantic hydrogen hubs to mature, and high-grade steel recycling supply chains to emerge, indicating alternative pathways to high-grade steel. From there, other decarbonization opportunities at steel facilities may be more attractive, such as direct reduced iron (DRI) using hydrogen coupled with electric arc furnaces.

But for now, Pennsylvania took the first step toward large-scale industrial decarbonization. These first-of-a-kind demonstrations are pivotal in achieving commercial CCS on steel and Edgar Thompson will begin proving CCS on blast furnaces. Steel facilities hosting blast furnaces with long lifetimes could follow this path, while others may invest in alternate decarbonization approaches. Through its national labs, DOE will combine incumbent and emerging decarbonization technologies to bridge technological gaps.

This figure is a pie chart of the CO2 emissions from the iron and steel industry. The pie chart is divided into three broad categories: high-grade steel, low-grade steel and recycling, and coking facilities. Each of these three broad categories is broken down into the emitting units associated with that process. Each pie slice is labelled with the emitting unit and the percentage of CO2 emissions associated with the unit. These labels and numbers are as follows:

Within high-grade steel:
●	Blast furnace makes up 50% of the pie
●	Basic oxygen furnace makes up 6% of the pie
●	Coking makes up 2% of the pie
●	Others (including flaring, onside electricity generation, and downstream operations) makes up 1% of the pie
Within low-grade steel & recycling:
●	Stationary combustion makes up 13% of the pie
●	Electric arc furnace makes up 3% of the pie
●	Direct reduction makes up less than 1% of the pie
●	Others (including coking, downstream operations, and others) makes up 4% of the pie
Within coking facilities:
●	Coking makes up 18% of the pie
●	Stationary combustion makes up 2% of the pie
●	Flaring makes up less than 1% of the pie
Figure 3: CO2 emissions for the iron and steel industry in Pennsylvania broken down by type of facility and source

In Figure 2, we partitioned industrial emissions by sector, showing capturable emissions versus remaining emissions, and in Figure 3 further delineated the steel sector. Half of Pennsylvania’s steel emissions come from blast furnaces at Edgar Thompson, units on which carbon capture will be demonstrated. Many of the sector’s emissions come from coking and coke oven gas (COG) processes. Coke usage in steelmaking produces COG, which is reused onsite to create power. Alternative pathways that eliminate coking activities will eliminate the CO2 emissions produced from COG but will need further investigation to determine how fuel replacement compares with emissions introduced from virgin heat and power sources.

This image portrays a map of Pennsylvania with geospatial data that relates to Pennsylvania’s position to utilize CCS as a decarbonization option. Throughout various parts of the state, the following resources and installations can be found:
●	Point source carbon capture sites
●	Carbon removal sites
●	Class VI wells awaiting EPA permitting
●	Carbon conversion sites
●	CarbonSAFE Phase III sites, and
●	Sedimentary storage potential
These are complemented by Hydrogen hubs, and Pre-FEED CO2 pipeline corridors. The main concentrations of these sites are illustrated in the Western part of the state, surrounding Pittsburgh, and the Eastern part of the state, encompassing Philadelphia and Allentown.
Figure 4: Industries where carbon capture could be implemented in Pennsylvania, along with carbon storage potential and DOE-funded projects in carbon capture, removal, transportation, and storage (data from the EPA-FLIGHT database, Roads to Removal, and NETL).

Collocation of industrial emissions to storage, including CarbonSAFE Phase 3 sites, suggests the emergence of carbon hubs (Figure 4). Similar to DAC or hydrogen hubs, carbon hubs group emission sources and sinks interconnected with CO2 transport. The steel hub around Pittsburgh includes glass, petrochemical, and cement facilities.

Nearby in Ohio is a CarbonSAFE location, the recommended CO2 sink for these Pittsburgh emissions. This hub is within the Appalachian hydrogen hub and Transport Corridor, and proximal to the CCS Hub at NETL Pittsburgh. Another carbon hub is by Allentown, where cement facilities are clustered. These cement facilities could unite and apply for a CarbonSAFE Phase 1 permit as they are located above potentially viable CO2 storage geology. These facilities could partner with the Mid-Atlantic hydrogen hub.

As Pennsylvania progresses in industrial decarbonization and leads the charge on low carbon steel, policymakers must consider justice practices, leveraging engagement work to make educated choices: in decarbonization deploy dialogues, participants stressed the need for efficient flow of materials, energy, and resources across the value chain. They identified barriers like lacking transport and storage infrastructure, and technologies supporting smaller-scale CCS.

Smaller-scale CCS should consider CO2 transportation by truck; it’s economical for smaller quantities and shorter distances—the capture of less than 70,000 tCO2/yr would require less than ten truckloads per day.

For large facilities, pipelines benefit from economies of scale but can face community resistance. Rail can be an intermediate option for CO2 transport as coal transport decreases with coal mine and coal power plant closures in Pennsylvania, maintaining jobs in the rail industry. Diligent community benefits plans will streamline development and implementation, making these projects sustainable because of the tangible benefits received by the community: workforce training, jobs, and cleaner air. These benefits also increase bonus funding through RISE PA. Supporting the deployment of carbon management technologies requires scalable policy incentives, such as the 45Q tax credit, which could be tailored to meet the needs of specific regions over time.

Shelvey Swett

PhD Candidate , Chemical and Biomolecular Engineering

Shelvey Swett is a third year PhD candidate in the Chemical and Biomolecular Engineering department at the University of Pennsylvania. Her work focuses on carbon capture and storage and on the recovery of critical minerals.

Maxwell Pisciotta

Postdoctoral Fellow, Clean Energy Conversions Lab

Max Pisciotta is a postdoctoral fellow in the Clean Energy Conversions Lab. They hold a PhD in Chemical Engineering from Penn whose research focused on carbon capture and carbon removal. They served on the Kleinman Center Student Advisory Board and completed the 2021 Kleinman Birol Fellowship.

Hélène Pilorgé

Research Associate, Clean Energy Conversions Lab

Hélène Pilorgé is a research associate with the University of Pennsylvania’s Clean Energy Conversions Laboratory. Her research focuses on carbon accounting of various carbon management solutions and on Geographic Information Systems (GIS) mapping for responsible deployment of carbon management.

Shrey Patel

PhD Candidate , Chemical and Biomolecular Engineering

Shrey Patel is a second year PhD candidate in the Department of Chemical and Biomolecular Engineering at the University of Pennsylvania. His research focuses on the integration of low carbon energy sources with carbon capture and storage.

Jennifer Wilcox

Presidential Distinguished Professor

Jen Wilcox is Presidential Distinguished Professor of Chemical Engineering and Energy Policy. Her research expertise is in carbon capture and sequestration technologies, in order to minimize the negative impacts of fossil fuels.